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Effect of Accelerated High Temperature on Oxidation and Polymerization of Biodiesel from Vegetable Oils

Author

Listed:
  • Jae-Kon Kim

    (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority, Cheongju 28115, Korea
    Co-first authors.)

  • Cheol-Hwan Jeon

    (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority, Cheongju 28115, Korea
    Co-first authors.)

  • Hyung Won Lee

    (School of Environmental Engineering, University of Seoul, Seoul 02504, Korea)

  • Young-Kwon Park

    (School of Environmental Engineering, University of Seoul, Seoul 02504, Korea)

  • Kyong-il Min

    (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority, Cheongju 28115, Korea)

  • In-ha Hwang

    (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority, Cheongju 28115, Korea)

  • Young-Min Kim

    (Department of Environmental Sciences and Biotechnology, Hallym University, Chuncheon 24252, Korea)

Abstract
Oxidation of biodiesel (BD) obtained from the decomposition of biomass can damage the fuel injection and engine parts during its use as a fuel. The excess heating of vegetable oils can also cause polymerization of the biodiesel. The extent of BD oxidation depends on its fatty acid composition. In this study, an accelerated oxidation test of BDs at 95 °C was investigated according to ASTM D 2274 by applying a long-term storage test for 16 weeks. The density, viscosity, and total acid number (TAN) of BDs increased because of the accelerated oxidation. Furthermore, the contents of unsaturated fatty acid methyl esters (FAMEs), C18:2 ME, and C18:3 ME in BDs decreased due to the accelerated oxidation. The 1 H-nuclear magnetic resonance spectrum of BDs that were obtained from the accelerated high temperature oxidation at 180 °C for 72 h differed from that of fresh BDs. The mass spectrum obtained from the analysis of the model FAME, linoleic acid (C18:2) methyl ester, which was oxidized at high temperature, indicated the formation of dimers and epoxy dimers of linoleic acid (C18:2) methyl ester by a Diels-Alder reaction.

Suggested Citation

  • Jae-Kon Kim & Cheol-Hwan Jeon & Hyung Won Lee & Young-Kwon Park & Kyong-il Min & In-ha Hwang & Young-Min Kim, 2018. "Effect of Accelerated High Temperature on Oxidation and Polymerization of Biodiesel from Vegetable Oils," Energies, MDPI, vol. 11(12), pages 1-11, December.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:12:p:3514-:d:191185
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    References listed on IDEAS

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    4. Nwafor, O.M.I, 2003. "The effect of elevated fuel inlet temperature on performance of diesel engine running on neat vegetable oil at constant speed conditions," Renewable Energy, Elsevier, vol. 28(2), pages 171-181.
    5. Yaakob, Zahira & Mohammad, Masita & Alherbawi, Mohammad & Alam, Zahangir & Sopian, Kamaruzaman, 2013. "Overview of the production of biodiesel from Waste cooking oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 184-193.
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    Cited by:

    1. Andra Lovasz & Nicu Cornel Sabau & Ioana Borza & Radu Brejea, 2023. "Production and Quality of Biodiesel under the Influence of a Rapeseed Fertilization System," Energies, MDPI, vol. 16(9), pages 1-27, April.
    2. Jakub Čedík & Martin Pexa & Michal Holúbek & Jaroslav Mrázek & Hardikk Valera & Avinash Kumar Agarwal, 2021. "Operational Parameters of a Diesel Engine Running on Diesel–Rapeseed Oil–Methanol–Iso-Butanol Blends," Energies, MDPI, vol. 14(19), pages 1-24, September.
    3. Anton L. Esipovich & Evgeny A. Kanakov & Tatyana A. Charykova & Ksenia V. Otopkova & Mikhail A. Smirnov & Yulia A. Mityukova & Artem S. Belousov, 2024. "A Comprehensive Study on Physicochemical Properties of Fatty Acid Esters Derived from Different Vegetable Oils and Alcohols and Their Potential Application," Energies, MDPI, vol. 17(24), pages 1-27, December.

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